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POLYLINK POLYMERS (INDIA) LTD.                                                              Products

Compounds for Power Cables

Silane Grafted Crosslinkable Polyethylene Black
for Low Voltage Power Cable Insulation / Sheath
Grade - XL-ABC-01

SPECIAL CHARACTERISTICS :

A silane grafted crosslinkable polyethylene black compound,curable by exposure to moisture, for insulation/sheath of power cables and possessing excellent extrudability at high out put rate.

XL-ABC-01 is based on a high molecular weight polymer. It has been specially developed for insulation of core of aerial bunched cable for overhead application.

DESCRIPTION :

This compound utilizes the system for cross-linking of polyethylene developed by DOW coming and known as Sioplas. It is a two component system comprising a silylated ethylene polymer alongwith suitable additives known as XL-ABC-01 the graft copolymer, and a master batch XL-ABC-BLK containing mainly carbon black,u.v.ingredients and a cross-linking catalyst.The two materials should be used in the ratio of 93.7 parts graft to6.3 parts catalyst master batch.

Stored separately,these materials are fairly stable but when mixed and exposed to moisture, cross – linking takes place.

This system allows the compound to be extruded as a normal thermoplastic which will then attain a high level of cross-linking in the processed form.The finished product has all the properties associated with polyethylene cross-linked by other methods.

TECHNICAL DATASHEET : 

Property

Test Method

Unit

Typical value

Density

ASTM-D-1505

gm / cm3

0.93

MFI at 190° C / 2.16 Kg.

PPIL

G / 10

0.4

Unaged mechanical properties:

     

Tensile Strength at Break

IEC811

MPa

18

Elongation at Break

IEC811

%

450

Mechanical Properties after ageing in Air oven, 168 hr. at 135° C :

     

Variation on tensile strength

IEC811

%

+10

Variation on elongation at break

IEC811

%

-15

Hot set test, 15 min. at 200° C, 0.2 N / mm2 :

     

Elongation under load

IEC811

%

100

Permanent Elongation after Cooling

IEC811

%

5

ESCR; 50° C, 10% lgepal soln.

IEC811

hr

>96

Carbon Black content

TGA

%

2.5

Carbon Black Dispersion

BS 2782; Part 8 method 823A

visual matching

matching no2 photo

* Material is protected against UV radiation.
* All properties are based on moulded/extruded material made from XL-ABC-01 and XL-ABC-BLK in the ratio of 97.3 : 6.3.

Electrical Properties :

 

   

Power factor at 50 Hz at 23° C

IEC250

Nil

0.0005

Dielectric constant IEC250  

2.3

Volume Resistivity at 23° C IEC93 Ohm.cm

2.4*1016

Dielectric Strength IEC243 Kv / mm

22



RECOMMENDED EXTRUSION CONDITIONS :


Extruder

Thermoplastic extruders will process PPIL siplas-type compound particularly if the screw is suitable for polyethylene extrusion. An extruder having L/D ratio of atleast 20 and compression of 3:0:1 is recommended.

Extrusion temperature conditions

As a guide the following temperature profile is recommended :-

Zone 1 Zone 2 Zone 3 Zone 4 Head Die
160° C 170° C 180° C 190° C 200° C 210° C

 

This profile may vary depending on extruder type design and out put.

Screw water temperature : 60ºC-70ºC 
Screens : 30,100,30 (mesh apertures per linear inch)

HEAD AND TOOL DESIGN : 

The head and tools should be so designed to allow streamline flow without the possibility of stagnation of material.

To obtain optimum physical properties in the case of tubing tools, it is generally recommended that a draw down ratio not greater than 2.8:1 should be used both for sector and round shaped conductor. PPIL engineers would be glad to provide comprehensive details of recommended tool design for both round and sector shaped conductor.

CROSSLINKING OR CURE :

Curing can be done in the following ways:
- By immersion in hot water at 70-80ºC
- By exposure to low pressure steam ( about 0.15 bar)
Following factors are important for cure,
- The ratio of conductor to insulation thickness
- Barrel diameter of the cable on which the core is cured

MASTER BATCH :

It is recommended that the catalyst masterbatch be thoroughly dried before usage at 60ºC for 18 hrs. at a depth not greater than 5 cm.

STORAGE :

Store under cold and dry conditions for best results

FORM AND PACKING :

Form : pellets

Packaging : Moisture resistant high density carboy containing 125 kg.

This information is to the best of our knowledge. The values of different parameters and operating conditions listed above are guidance only and should not be used for drawing specifications. The results & operating conditions may vary depending on methods of test and manufacturing / testing equipments.